Why is Phoebe always mean to Chandler?
There's no instance in the show which can prove your point. She might not like them as much as she likes others (Joey, Monica and Rachel) but she doesn't hate them. For instance, she named one of her triplets Chandler because she didn't want Chandler to think that his name was not good enough.
In season five, the series teased a potential romantic relationship between these two. Of course, this forced connection between Phoebe and Chandler was never real. It was only a way for the gang to get Chandler to come clean about his secret relationship with Monica.
Friends - Clip - Phoebe Tries to Seduce Chandler - Promo Trailer HD - In order to pressure Chandler into revealing his relationship with Monica, Phoebe tries to seduce him. She pulls out all the stops, and Chandler ultimately breaks, revealing his love for Monica to the friend group.
Although not as intense as a full diagnosis of schizophrenia, Phoebe does have a schizotypal personality disorder. This disorder has symptoms of unusual beliefs and perceptions, illogical ideas, minor hallucinations, strange emotional responses and memory problems.
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Phoebe Spengler, granddaughter of Ghostbuster Egon saves the day in the latest supernatural sequel. What they don't mention is that heroine Phoebe is neurodivergent, and it is her autistic personality traits that make her a hero. Not to worry, no spoilers here.
Monica. Monica is the love of Chandler's life, his best friend, his rock, and the two are arguably the best couple of the show.
For those who do not have enough time, here is the short version: Joey was the best friend, followed by Ross, while Rachel was the worst friend by far.
Craig Bierko (Cinderella Man) was the first choice for Chandler but he turned it down, oddly enough to film a different pilot called Best Friends which never made it to air.
Phoebe Buffay is a classic example of an ENFP. Imaginative and original, these individuals are often very artistic, even in appearance. They are unconventional and tend to develop a distinctive and quirky personal style.
Who turned down the role of Phoebe on Friends?
After auditioning for the role of Rachel, the producers were believed to have had Jane Krakowski in mind for the role. Meanwhile, Ellen DeGeneres was actually the producers' first choice to play Phoebe, but she turned it down – although considering she's now a talk show queen, we reckon she's done alright.
Diagnosis. The character of Phoebe displays symptoms of both ADHD and Asperger`s syndrome. On the ADHD side, Phoebe is extremely hyperactive. Symptoms of ADHD seen in adults is restlessness, which as example, when she`s upset, she eats her hair.

Tied for second place in the sleeping-around category were Phoebe Buffay (Lisa Kudrow) and Ross Gellar (David Schwimmer), who each had 16 partners, although 37.5 percent of Phoebe's relationships were serious, while half of Ross' relationships wound up being long-term.
References
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- https://screenrant.com/friends-phoebe-chandler-perfect-couple/
- https://www.quora.com/Why-does-Phoebe-hate-Chandler-and-Ross
- https://rss.onlinelibrary.wiley.com/doi/10.1111/1740-9713.01574
- https://www.insider.com/friends-interesting-things-to-know-about-phoebe-buffay-fun-facts-2022-1
- https://dorizener.com/ghostbuster-phoebe-spengler-the-ultimate-autistic-hero/
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- https://www.latestly.com/lifestyle/health-wellness/world-mental-health-day-2019-was-phoebe-buffay-from-friends-schizophrenic-popular-fan-theory-says-so-1258657.html
- https://screenrant.com/myers-briggs-personality-types-friends-characters/
- https://prezi.com/zvqzt6behpyp/the-many-personalities-of-phoebe-buffay/
- https://www.thehealthyjournal.com/faq/who-turned-down-a-role-in-friends
- https://nypost.com/2011/07/28/friends-sex-lives-by-the-numbers/